Hanson Chemicals

Polymethacrylates (PMA)

Formula: (C₅H₈O₂)ₙ
CAS Number: 9011-14-7 (general)
EC Number (EINECS): 208-750-2 (varies by polymer grade)
HS Code: 39069090
UN Number: Not classified as hazardous for transport
IUPAC Name: Poly(2-methylprop-2-enoate)
Also Known As: PMA; Poly(methyl methacrylate-co-methacrylic acid); Methacrylate Polymers
Molecular Weight, g/mol: Variable (depends on grade & application)

Typical Specifications

Appearance: White/off-white powder or granules; sometimes liquid dispersion
Odor: Odorless
Density, g/cm³ (at 20°C): 1.15–1.20
Solubility: Insoluble in water; soluble in esters, ketones, and chlorinated hydrocarbons
Purity, %: ≥99 (monomer conversion)
Grades Available: Industrial, Technical, Coating Grade, Specialty Grades
Packaging: 25kg bags, 500kg jumbo bags, liquid drums/IBCs (for emulsions)

Applications / Uses

Primary Applications

  • Binder in paints, inks, and coatings

  • Modifier for adhesives and sealants

  • Component in plastics and polymer blends

  • Rheology modifier in lubricants and fuels

Secondary Applications

  • Used in construction chemicals (concrete admixtures, waterproofing)

  • Ingredient in cosmetic formulations (film-forming agents, hair fixatives)

  • Automotive and industrial coatings

  • Leather and textile finishing

End Industries Served: Paints & Coatings, Adhesives, Plastics, Construction, Automotive, Cosmetics, Textiles, Lubricants

Safety & Handling Information

Hazard Class (GHS): Generally considered non-hazardous; dust may cause irritation

Hazard Statements (H-Codes):

  • H319: Causes serious eye irritation (dust)

  • H335: May cause respiratory irritation (dust)

  • H402: Harmful to aquatic life (for some modified PMA grades)

Precautionary Statements (P-Codes):

  • P280: Wear protective gloves/eye protection

  • P261: Avoid breathing dust/fumes

  • P273: Avoid release to the environment

Storage Conditions

  • Store in a dry, cool, ventilated area

  • Avoid heat, sparks, or open flames

  • Protect from moisture and contamination

Transport Information

  • ADR/RID: Not classified as dangerous goods

  • IMDG: Not classified as dangerous goods

  • IATA: Not classified as dangerous goods

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