Hanson Chemicals

Polymeric MDI

Formula: (C₁₅H₁₀N₂O₂)n
CAS Number: 9016-87-9
EC Number (EINECS): 618-498-9
HS Code: 29269090
UN Number: 2078
IUPAC Name: 4,4'-Methylenediphenyl Diisocyanate, Polymer
Also Known As: PMDI; Polymer MDI; Polymeric Diphenylmethane Diisocyanate
Molecular Weight, g/mol: 250–500 (average, polymeric mixture)

Typical Specifications

Appearance: Brownish, viscous liquid or pasty solid
Odor: Pungent, characteristic isocyanate odor
Melting Point, °C: 40–50
Boiling Point, °C: Decomposes before boiling
Flash Point, °C: >200 (closed cup)
Solubility: Insoluble in water, soluble in aromatic solvents
Purity, %: ≥98
Packaging: 200kg drums, 1000kg IBC

Applications / Uses

Primary Applications

  • Production of flexible and rigid polyurethane foams

  • Raw material for coatings, adhesives, sealants, elastomers (CASE)

  • Component in composite wood products (particleboard, MDF)

Secondary Applications

  • Manufacture of specialty polymers and elastomeric components

  • Industrial coatings and insulation materials

End Industries Served: Polyurethane Foam, CASE (Coatings, Adhesives, Sealants, Elastomers), Construction, Automotive, Furniture, Insulation

Safety & Handling Information

Hazard Class (GHS): Skin sensitizer (Category 1), Acute Toxicity (Category 4), Respiratory sensitizer (Category 1)

Hazard Statements (H-Codes):

  • H315: Causes skin irritation

  • H317: May cause allergic skin reaction

  • H319: Causes serious eye irritation

  • H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary Statements (P-Codes):

  • P260: Do not breathe dust/fume/gas/mist/vapors/spray

  • P280: Wear protective gloves/eye protection/face protection

  • P302 + P352: IF ON SKIN – wash with plenty of water

  • P304 + P341: IF INHALED – remove person to fresh air and keep comfortable for breathing

Storage Conditions

  • Store in a cool, dry, well-ventilated area

  • Keep containers tightly closed

  • Protect from moisture and humidity (reactive with water)

Transport Information

  • ADR/RID: Class 6.1, UN2078, PG II

  • IMDG: Class 6.1, UN2078

  • IATA: Class 6.1, UN2078

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