Hanson Chemicals

Phenolic Antioxidants

Formula: Varies (general class of compounds; e.g., BHT – C₁₅H₂₄O, BHA – C₁₁H₁₆O₂)
CAS Number: BHT – 128-37-0; BHA – 25013-16-5; TBHQ – 1948-33-0
EC Number (EINECS): Varies by compound (e.g., BHT – 202-764-5, BHA – 202-967-7)
HS Code: 29142990 (for hindered phenols and derivatives)
UN Number: Not classified as hazardous for transport (varies by specific antioxidant)
IUPAC Name: Typically alkylated phenols (e.g., 2,6-di-tert-butyl-4-methylphenol for BHT)
Also Known As: Hindered Phenols; BHT (Butylated Hydroxytoluene); BHA (Butylated Hydroxyanisole); TBHQ (Tert-Butylhydroquinone)
Molecular Weight, g/mol: Depends on compound (e.g., BHT – 220.35, BHA – 180.25)

Typical Specifications

Appearance: White to slightly yellow crystalline powder or flakes
Odor: Mild, characteristic
Melting Point, °C: BHT: 69–71; BHA: 48–63; TBHQ: 126–128
Boiling Point, °C: Decomposes before boiling
Density, g/cm³ (at 20°C): ~1.05–1.06
Flash Point, °C: >110 (closed cup, varies by compound)
Solubility: Insoluble in water; soluble in fats, oils, and organic solvents
Purity, %: ≥99
Grades Available: Food Grade, Industrial Grade
Packaging: 25kg bags, fiber drums, cartons

Applications / Uses

Primary Applications

  • Widely used as antioxidants in polymers and plastics to prevent oxidative degradation

  • Added to lubricants and fuels to extend stability and performance

  • Essential in food industry (specific phenolics like BHT, BHA, TBHQ) to stabilize edible oils, fats, and packaged foods

Secondary Applications

  • Used in cosmetics and personal care products to protect against rancidity

  • Ingredient in adhesives, coatings, and rubbers

  • Intermediate in specialty chemicals

End Industries Served: Plastics, Polymers, Food & Beverages, Lubricants, Cosmetics, Packaging, Rubber, Adhesives, Coatings

Safety & Handling Information

Hazard Class (GHS): Generally classified as harmful or irritant depending on compound

Hazard Statements (H-Codes):

  • H315: Causes skin irritation

  • H319: Causes serious eye irritation

  • H335: May cause respiratory irritation

  • H351: Suspected of causing cancer (for some phenolic antioxidants under certain conditions)

Precautionary Statements (P-Codes):

  • P261: Avoid breathing dust/fumes

  • P280: Wear protective gloves/eye protection

  • P302 + P352: IF ON SKIN – wash with soap and water

  • P305 + P351 + P338: IF IN EYES – rinse cautiously with water, remove contact lenses if present

Storage Conditions

  • Store in tightly sealed containers, away from heat and direct sunlight

  • Protect from moisture and strong oxidizing agents

  • Keep in cool, ventilated storage areas

Transport Information

  • ADR/RID: Not classified as dangerous goods

  • IMDG: Not classified as dangerous goods

  • IATA: Not classified as dangerous goods

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